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Solid oxygen forms at normal atmospheric pressure at a temperature below 54.36 K (−218.79 °C, −361.82 °F). Solid oxygen O[SUB]2[/SUB], like liquid oxygen, is a clear substance with a light sky-blue color caused by absorption in the red.
Oxygen molecules have attracted attention because of the relationship between the molecular magnetization and crystal structures, electronic structures, and superconductivity. Oxygen is the only one of the simple diatomic molecules (and one of the few molecules in general) to carry a magnetic moment. This makes solid oxygen particularly interesting, as it is considered a 'spin-controlled' crystal that displays unusual magnetic order. At very high pressures, solid oxygen changes from an insulating to a metallic state; and at very low temperatures, it even transforms to a superconducting state. Structural investigations of solid oxygen began in the 1920s and, at present, six distinct crystallographic phases are established unambiguously.
The density of solid oxygen ranges from 21 cm[SUP]3[/SUP]/mol in the α-phase, to 23.5 cm[SUP]3[/SUP]/mol in the γ-phase.
As the pressure of oxygen at room temperature is increased through 10 GPa, it undergoes a dramatic phase transition to a different allotrope. Its volume decreases significantly, and it changes color from blue to deep red. This ε-phase was discovered in 1979, but the structure has been unclear. Based on its infrared absorption spectrum, researchers assumed in 1999 that this phase consists of O[SUB]4[/SUB] molecules in a crystal lattice. However, in 2006, it was shown by X-ray crystallography that this stable phase known as
ε oxygen or
red oxygen is in fact O[SUB]8[/SUB]. No one predicted the structure theoretically: a rhomboid O[SUB]8[/SUB] cluster consisting of four O[SUB]2[/SUB] molecules.
In this phase it exhibits a dark-red color, very strong infrared absorption, and a magnetic collapse. It is also stable over a very large pressure domain and has been the subject of numerous X-ray diffraction, spectroscopic and theoretical studies. It has been shown to have a monoclinic C2/m symmetry and its infrared absorption behaviour was attributed to the association of oxygen molecules into larger units.
- Liquid oxygen is already used as an oxidant in rockets, and it has been speculated that red oxygen could make an even better oxidant, because of its higher energy density.
- Researchers think that this structure may greatly influence the structural investigation of elements.
- It is the phase that forms above 600 K at pressures greater than 17 GPa.
- At 11 GPa, the intra-cluster bond length of the O[SUB]8[/SUB] cluster is 0.234 nm, and the inter-cluster distance is 0.266 nm. (For comparison, the intra-molecular bond length of the oxygen molecule O[SUB]2[/SUB] is 0.120 nm.)
- The formation mechanism of the O[SUB]8[/SUB] cluster found in the work is not clear yet, and the researchers think that the charge transfer between oxygen molecules or the magnetic moment of oxygen molecules has a significant role in the formation.
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اما این مقاله داره به معرفی اکسیژن جامد و شرایط نگه داری اون می پردازه{اسم دیگش اکسیژن قرمز}(o8)
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